In saltwater, the water concentration is lower outside the plant cells than inside, so water moves out of the cells by osmosis. This loss of water causes the plant cells to become plasmolyzed, which means that they shrink and pull away from the cell wall. Plasmolysis can damage the cell membrane and disrupt the plant's metabolism, eventually leading to death.
Some plants have evolved adaptations that allow them to tolerate high levels of salinity, but most freshwater plants cannot survive in saltwater.
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